{"id":155512,"date":"2021-02-26T14:22:01","date_gmt":"2021-02-26T14:22:01","guid":{"rendered":"http:\/\/blog.hannaservice.eu\/electrode-selective-dions\/"},"modified":"2022-10-10T10:52:14","modified_gmt":"2022-10-10T10:52:14","slug":"electrode-selective-dions","status":"publish","type":"post","link":"https:\/\/blog.hannaservice.eu\/fr\/electrode-selective-dions\/","title":{"rendered":"\u00c9lectrode s\u00e9lective d’ions"},"content":{"rendered":"\t\t
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Hanna propose une solution pour chaque m\u00e9thode d’analyse ionique potentiom\u00e9trique avec des \u00e9lectrodes s\u00e9lectives d’ions.
\nLes analyses potentiom\u00e9triques d’ions avec des \u00e9lectrodes s\u00e9lectives d’ions (ISE) sont effectu\u00e9es \u00e0 l’aide de l’une des trois m\u00e9thodes, chacune comportant ses propres avantages : potentiom\u00e9trie directe, m\u00e9thodes incr\u00e9mentielles et titrage potentiom\u00e9trique. Hanna propose une solution pour chacune de ces m\u00e9thodes\u00a0:<\/p>\n

Potentiom\u00e9trie directe<\/strong><\/p>\n

La potentiom\u00e9trie directe<\/strong> est une m\u00e9thode largement utilis\u00e9e pour effectuer une analyse ionique avec des ISE. Cette m\u00e9thode est tr\u00e8s efficace lorsque l’utilisateur doit mesurer rapidement de grands lots d’\u00e9chantillons \u00e0 des concentrations variables.<\/p>\n

Nos compteurs \u00e0 lecture directe, tels que le HI98191, affichent la concentration de l’\u00e9chantillon inconnu par une lecture directe apr\u00e8s \u00e9talonnage de l’instrument avec deux normes ou plus\u00a0; des ajustements de la force ionique sont effectu\u00e9s \u00e0 la fois sur les \u00e9chantillons et les normes.<\/p>\n

M\u00e9thodes incr\u00e9mentales<\/strong>
\nLes m\u00e9thodes incr\u00e9mentielles sont des techniques utiles utilis\u00e9es pour d\u00e9terminer la concentration en ions dans des \u00e9chantillons dont les constituants sont variables ou concentr\u00e9s. Les m\u00e9thodes incr\u00e9mentielles pr\u00e9sentent certains avantages inh\u00e9rents par rapport \u00e0 la potentiom\u00e9trie directe. Les techniques peuvent r\u00e9duire les erreurs de variables telles que la temp\u00e9rature, la viscosit\u00e9, le pH ou la force ionique.<\/p>\n

Les \u00e9lectrodes restent immerg\u00e9es tout au long du processus, r\u00e9duisant ainsi le transfert d’\u00e9chantillon et les changements possibles de jonction liquide dans la r\u00e9f\u00e9rence. Les m\u00e9thodes connues d’addition, de soustraction, d’addition d’analyte et de soustraction d’analyte sont quatre de ces techniques incr\u00e9mentielles.<\/p>\n

Un titrage potentiom\u00e9trique peut augmenter la pr\u00e9cision des mesures ISE ainsi que le nombre d’esp\u00e8ces ioniques pouvant \u00eatre d\u00e9termin\u00e9es. Les ISE sont couramment utilis\u00e9s comme indicateurs pour le titrant ou l’\u00e9chantillon d’esp\u00e8ces pour suivre la progression d’une pr\u00e9cipitation ou complexom\u00e9trique.<\/p>\n

Titrage<\/strong>
\nUn petit changement dans l’ajout de r\u00e9actif correspond \u00e0 un grand changement de potentiel d’\u00e9lectrode au point final stoechiom\u00e9trique. Un exemple de titrage par pr\u00e9cipitation est la d\u00e9termination du chlorure \u00e0 l’aide de nitrate d’argent. Un ISE d’argent peut \u00eatre utilis\u00e9 pour suivre ce titrage.<\/p>\n

Un titrage complexom\u00e9trique est utilis\u00e9 pour la d\u00e9termination du calcium. Une solution de calcium est titr\u00e9e avec l’agent complexant, l’EDTA. Pendant le titrage, il y a une diminution progressive de la concentration en ions Ca2+ libres \u00e0 mesure que plus d’EDTA est ajout\u00e9. Le point final correspond au point auquel tout le Ca2+ est complex\u00e9. L’avancement de ce titrage peut \u00eatre suivi \u00e0 l’aide d’un ISE calcium.<\/p>\n

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Hanna propose une solution pour chaque m\u00e9thode d’analyse ionique potentiom\u00e9trique avec des \u00e9lectrodes s\u00e9lectives d’ions. […]<\/p>\n","protected":false},"author":14,"featured_media":2813,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"default","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"default","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[398],"tags":[300],"class_list":["post-155512","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-laboratoire","tag-electrodes-fr"],"yoast_head":"\n\u00c9lectrode s\u00e9lective d'ions - Hanna Instruments Maroc<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/blog.hannaservice.eu\/fr\/electrode-selective-dions\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"\u00c9lectrode s\u00e9lective d'ions - Hanna Instruments Maroc\" \/>\n<meta property=\"og:description\" content=\"Hanna propose une solution pour chaque m\u00e9thode d’analyse ionique potentiom\u00e9trique avec des \u00e9lectrodes s\u00e9lectives d’ions. 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