Wastewater

From inflow to outflow, we have everything under control.

Technology that takes your testing beyond the standard.

Wastewater is water used for domestic, industrial, or agricultural activities that, due to human activity, may contain organic or inorganic substances that are potentially harmful to health and the environment. This wastewater must be monitored and treated before being reintroduced into the environment (into the soil, rivers, lakes, or seas) to avoid endangering the normal balance of the ecosystem.

Wastewater discharged into local water supply systems, including sewers, must comply with the wastewater control standards established by the government. It is important to test several parameters to ensure public safety and prevent damage to wastewater treatment processes and the environment.

The main parameter analyzed to assess the content of biodegradable organic matter is COD (chemical oxygen demand), which is often supplemented by BOD (biochemical oxygen demand).

Biochemical oxygen demand

Biochemical oxygen demand. The amount of oxygen required by aerobic microorganisms to absorb and degrade the organic substances present in the wastewater. This value increases with the amount of organic matter present in the wastewater. The measurement of the oxygen present in the measuring cells after five days of incubation yields BOD5, and after 20 days, BOD20.

Chemical oxygen demand

Chemical Oxygen Demand. This is a metric used to measure the amount of oxygen required to chemically oxidize the oxidizable substances present in wastewater

Chemical oxygen demand (COD) is an important metric for waste treatment in all sectors, from municipal systems to food production waste streams.

Proper COD testing is important for determining the effectiveness of wastewater treatment and can help diagnose treatment problems. The COD method is also used in power plants, the chemical industry, the paper industry, laundries, environmental studies, and general education. The efficiency of the treatment process is usually expressed as the percentage of oxidizable substances removed during the cycle.

In water treatment plants, the COD value must be less than 10 mg/L O2 at the end of the treatment cycle.

In general, the pH of the water discharged from wastewater treatment plants can vary. The goal is to maintain a neutral pH, i.e., around 7.

Depending on the composition of the industrial wastewater, the effluent pH can be high or low. Since the pH of industrial wastewater fluctuates greatly, it must be properly adjusted before it enters the biochemical tank or is discharged. For example, if the wastewater is highly acidic, a base must be added to adjust the pH.

Dissolved oxygen (DO) is a relative measure of the amount of oxygen (O2) dissolved in water. Oxygen levels must be considered and maintained in a wastewater treatment plant. A level of approximately 2 mg/L should be sufficient for biological processes. Bacteria and microorganisms utilize dissolved oxygen to decompose organic matter, thereby reducing the oxygen concentration. During wastewater treatment, microorganisms are added in flocs to aerobically digest and remove organic matter. Consequently, effective treatment depends on the health of the microorganisms and the dissolved oxygen concentration.

Electrical conductivity testing is essential in wastewater monitoring because it relates to the quantification of total dissolved solids in the water.

The conductivity (or specific conductivity) of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m).

EC can be used to randomly check and evaluate the performance of water purification systems, so any deviation from the trend may indicate contamination or a leak in the sewer system.

It is linked to TDS via a correlation factor.

Is a measure of the amount of all dissolved substances, which can include contaminants, minerals, salts, and other chemicals present in wastewater.

Since TDS measurements are often estimated using electrical conductivity (EC), it is assumed that the dissolved solids are predominantly ionic, with a concentration low enough to result in a linear TDS-EC relationship:

TDS [mg/L] = kₑ × EC [μS/cm]
where:
EC – electrical conductivity of the water at 25°C; and
kₑ – multiplier or conversion factor.
The value of kₑ increases with the increase in the number of ions in the water. It ranges from 0.5 to 0.8, but 0.67 is typically used.

Turbidity is an optical measurement that indicates the presence of suspended particles. It is measured by shining light through a sample and quantifying the concentration of suspended particles. The more particles in a solution, the higher the turbidity. In drinking water and municipal wastewater treatment plants, turbidity is often removed using a combination of sand filtration, settling tanks, and clarifiers.

(including copper, chromium, iron)

Like other elements, phosphorus is healthy and, in limited amounts, even necessary. However, excessive amounts of phosphorus can cause a type of pollution known as eutrophication. This is a process that leads to the aggressive stimulation of algae and other simple plants.

Total phosphorus (TP) is a measure of the total phosphorus found in a sample, regardless of whether it is dissolved or particulate.

Wastewater and sludge contain nitrogen in the form of organic nitrogen, ammonia (NH3) or ammonium (NH4+), nitrate (NO3-), and nitrite (NO2-).

During wastewater treatment, urea is converted into ammonia nitrogen. Because ammonia has a high demand for BOD and chlorine, high levels of ammonia in wastewater are undesirable. The process of nitrification is used to convert ammonia into nitrates.

Excess nitrogen can excessively stimulate the growth of aquatic plants and algae. Excessive growth of these organisms can, in turn, clog water inlets, consume dissolved oxygen during decomposition, and block light in deeper waters.</p>

(anionic, ionic, and cationic)

COD - Chemical Oxygen Demand

Digestion heating block / COD reactor

HI839800

Thermal heating block for cuvettes

COD testing requires digestion, so a heating block for your samples is crucial for accurate and repeatable results. For best results, choose a heating block that offers multiple temperatures so you can also perform other tests, such as total phosphorus. Most heating blocks also have timers, which are critical for maintaining digestion times across multiple runs.

For added safety, look for models that optionally come with a protective shield to cover the heating block in case of an accident.
The HI839800 COD Test Tube Heater is an easy-to-use thermoreactor made from durable materials. The aluminum block has a capacity of 25 test tubes and a recess for a reference temperature probe.
The clearly labeled user interface allows for intuitive operation. It features two arrows for setting the integrated timer and a temperature button with two preset temperature settings: 150ºC and 105ºC. Other features include status indicators, a thermal cutout to protect against overheating, and a continuous LCD display.

Das HI97105 ist für die genaue Bestimmung von pH-Wert, Alkalinität, Kalzium, Nitrat, Nitrit und Phosphat in meeresbiologischen Anwendungen konzipiert.

Photometer OR spectrophotometer

HI801

Spectrophotometer

Your partner in perfecting photometric laboratory analyses: the Hanna visible spectrophotometer. Unlike photometers, Iris measures all wavelengths of visible light, not just predefined wavelengths, to ensure complete method compliance and accuracy.

The convenience of pre-programmed methods with the ability to expand them.

Iris comes pre-programmed with more than 80 commonly used chemical analysis methods to get you started. Update these methods easily by connecting to a computer or flash drive.

Up to 250 methods (standard and user-defined)

  • Equipped with 85 pre-programmed methods (expandable to 150)
  • Up to 100 user-configurable methods

Optical system with reference beam technology (slit beam)

  • Spectral range 340-900 nm
  • Street light < 0.1% T
  • Bandwidth 5 nm
  • Accuracy ±1.5 nm

For all cuvette types

  • Automatic cuvette recognition
    10 and 50 mm rectangular cuvettes, 16 or 22 mm round cuvettes, 13 mm vials

Memory for up to 9,999 measurements

Portable COD and water analyzers photometer

HI83399

Water and Wastewater Multiparameter (with COD) Photometer and pH Meter

Monitor the levels of biological and chemical nutrients in your wastewater to ensure compliance with regulatory requirements. An innovative optical design ensures measurement consistency. To save valuable bench space, the HI83399, with its digital pH/temperature electrode input, can also be used as a professional pH meter. Specifically designed for the water industry, the HI83399 measures 40 different key quality parameters for water and wastewater.

  • Up to 77 water quality parameters
  • Portable
  • Also works with a rechargeable battery
  •  Autonomy of up to 500 measurements
  • Case for field analysis (optional)
  • Advanced optical system 
  • Precision ±1 nm 
  • Higher efficiency LED light source
  • High-quality narrowband interference filters
  • Digital pH electrode input
  • Also works as a pH meter!
  • Data storage and USB 

HI83324

Multiparameter photometer with COD and barcode detection for wastewater analysis

The HI83224 COD Meter and Multiparameter Photometer for measuring chemical oxygen demand (COD) and specific ions combines accuracy and ease of use in an ergonomic benchtop design. This meter is one of the most versatile photometers on the market, offering 15 measurement methods for various parameters, including COD, using ready-to-use liquid or powder reagents. The HI83224 incorporates numerous advanced features, including barcode recognition of sample vials, a graphic LCD display for displaying various chemical forms, and a step-by-step guide mode for inexperienced users.

HI83314

Multiparameter photometer for wastewater treatment with pH meter

The HI83314 is a compact multi-parameter photometer for measuring key water and wastewater quality parameters. Ten key water and wastewater quality parameters with 20 different methods covering multiple ranges are programmed into the meter. Wastewater treatment degradation parameters include COD, total nitrogen, and total phosphorus, which are important for monitoring nutrient removal. To save valuable bench space, the HI83314 can also be used as a professional pH meter with its digital pH/temperature electrode input.

COD Pre - prepared reagents

Reagents are one of the most important components of the COD test system. These chemicals are responsible for the oxidation of organic matter. These COD vials are premixed and ready to use.

Several types of reagents are commercially available:

  • EPA-compliant reagents: These vials comply with EPA Method 410.4 and Standard Method 5220D. These reagents use the method formulation, which contains mercuric sulfate, potassium dichromate, and sulfuric acid. Choose these vials if your work requires you to report COD results to an agency that requires EPA methods.
  • ISO-compliant reagents: Their composition conforms to the methods of ISO 15705:2002. The composition of these COD vials is similar to EPA standards, so they also contain mercury.
  • Mercury-free reagents: Most COD vials contain mercury sulfate to eliminate chloride interference that would otherwise produce a falsely high COD value. COD-free vials do not contain mercury, which makes them more susceptible to chloride interference but significantly reduces the safety and environmental risks associated with handling mercury. Therefore, these reagents are ideal for routine analyses where no or very low chloride concentrations are expected.

HI98 Serie

The HI98 series portable meters offer a robust solution for obtaining laboratory-quality results on-site. A wide range of models for single- and multi-parameter measurements means you can find a meter suitable for use in any space.

Measurement of BOD and dissolved oxygen using optical technology

HI98198

Optical dissolved oxygen meter with BOD

The HI98198 optical dissolved oxygen meter makes measuring dissolved oxygen concentration a breeze. Optical DO technology requires no minimum flow rate, resulting in less fluctuation in readings. The quick-connect probe is perfect for field or laboratory use. It requires no membranes, no fill solution, and no warm-up time, so you can measure without hesitation.
LDO Luminescence Oximeter

Optical LDO Probe with Smart Cap Technology

  • IP68 Waterproof Digital Probe

No Maintenance

  • No Membranes or Electrolyte to Replace

For Difficult Applications

  • Maximum Precision at Very Low Oxygen Levels
  • Readings Even in the Absence of Fluid Movement and Minimal Amounts

Very Fast Reading

  • No Drift
  • AUTOEND Function Locks the Reading Once It Stabilizes

Requires No Frequent Calibration

  • Capability to Calibrate to Zero Oxygen

HI98193

Waterproof portable meter for dissolved oxygen and BO

The professional, waterproof HI98193 meter complies with IP67 standards and measures oxygen concentration, barometric pressure, BOD, and temperature.

BOD is calculated in mg per liter from the difference between the initial and final dissolved oxygen concentration.

HI9829

Waterproof multi-parameter pH/ISE/EC/DO/Turbidity meter with GPS function

Choose your individual configuration!
The HI9829 is a waterproof, portable multi-parameter meter for monitoring up to 14 different water quality parameters. The microprocessor-controlled multi-sensor probe allows for the measurement of key parameters such as pH, ORP, conductivity, dissolved oxygen, turbidity, and temperature.

Optional connection: ISE Ammonium, ISE Chloride, or ISE Nitrate.

  • LDO Luminescence Oximeter
  • GPS mapping measurements made easy!
  •  Turbidity
  •  Standalone Sensor

Dissolved Oxygen:

HI7609829-2 DO

pH:

HI7609829-0 pH
HI7609829-1 pH/ORP

ISE:

HI7609829-10 Ammonium ISE
HI7609829-11 Chloride ISE
HI7609829-12 Nitrate ISE

Conductivity:

HI7609829-3 EC

Conductivity and Turbidity:

HI7609829-4 EC/Turbidity

Portable pH/EC/DO Meter with Bluetooth - HI98494

Portable pH/EC/DO Meter with Bluetooth - HI98494

Measurements & Logging Measure up to 12 parameters. Don't lose important data with automatic interval logging of up to 45,000 samples or choose to log-on-demand to store measurement data for key p...

Multiparameter pH/ORP/EC/TDS/Salinity/DO/Pressure/ Temperature Waterproof Meter - HI98194

Multiparameter pH/ORP/EC/TDS/Salinity/DO/Pressure/ Temperature Waterproof Meter - HI98194

Details: The HI98194 is a waterproof portable logging multiparameter meter that monitors up to 12 different water quality parameters. Its multi-sensor probe allows for the measurement of key parameter...

Multiparameter pH/ORP/EC/Pressure/Temperature Waterproof Meter - HI98195

Multiparameter pH/ORP/EC/Pressure/Temperature Waterproof Meter - HI98195

The HI98195 is a waterproof portable logging multiparameter meter that monitors up to 9 different water quality parameters. Its multi-sensor probe allows for the measurement of key parameters includin...

Multiparameter pH/ORP/DO/Pressure/Temperature Waterproof Meter - HI98196

Multiparameter pH/ORP/DO/Pressure/Temperature Waterproof Meter - HI98196

The HI98196 is a waterproof portable logging multiparameter meter that monitors up to 9 different water quality parameters. Its multi-sensor probe allows for the measurement of key parameters includin...

The HI5000 series meters are perfect for any laboratory and support a wide range of pH electrodes as well as models that enable selective ion, conductivity and dissolved oxygen measurements.

Two channels

  • Two probes can be used simultaneously

Superior design

  • 5.7″ color graphic display
  • Touch keypad

Advanced features

  • pH calibration with up to 5 points
  • Measurements with ion-selective electrodes

Customizable interface

  • Simultaneous display of both channels
  • Graphical representation of measurements

Memory for up to 100,000 data points

The HI5222, HI5521 and HI5522 devices also have two channels, so you can measure two parameters simultaneously.

Laboratory Research Grade Two Channel Benchtop pH/mV/ISE Meter - HI5222

Laboratory Research Grade Two Channel Benchtop pH/mV/ISE Meter - HI5222

Research Grade Meter pH/ORP and EC/TDS/Resistivity/Salinity and Temperature HI5521-02

Research Grade Meter pH/ORP and EC/TDS/Resistivity/Salinity and Temperature HI5521-02

Research Grade Meter pH/ORP/ISE and EC/TDS/Resistivity/Salinity and Temperature HI5522-02

Research Grade Meter pH/ORP/ISE and EC/TDS/Resistivity/Salinity and Temperature HI5522-02

Electrical conductivity (EC)

Electrical conductivity should be measured during wastewater treatment so that we can assess which treatment process would be most efficient in removing pollutants and contaminants.

Research Grade Conductivity/TDS Meter HI5321

Research Grade Conductivity/TDS Meter HI5321

Customizable User Interface The user interface of the HI5321 allows the user to show measurements in various modes: basic measurement with or without GLP information, real-time graphing, and logging d...

Waterproof Portable EC/TDS/Resistivity/Salinity Meter - HI98192

Waterproof Portable EC/TDS/Resistivity/Salinity Meter - HI98192

The HI98192 is supplied with the HI763133 four-ring conductivity probe with a built-in temperature sensor. This technology allows for accurate readings that cover a complete range with a single sensor...

Turbidity

ISO Portable Turbidity Meter - HI98713

ISO Portable Turbidity Meter - HI98713

The HI98713 Precision ISO Turbidity Portable Meter is specially designed for water quality measurements, providing reliable and accurate readings, even within low turbidity ranges. The instrument is b...

ISO 7027 Compliant Benchtop Turbidity Meter

ISO 7027 Compliant Benchtop Turbidity Meter

The HI88713 Precision ISO Turbidity Benchtop Meter is specially designed for water quality measurements, providing reliable and accurate readings, even within low turbidity ranges. The instrument is b...

Advanced tools for advanced requirements

Hanna automatic titrators combine advanced performance with unbeatable value.

Mini Titrator for Measuring Titratable Alkalinity in Water and Wastewater - HI84531

Mini Titrator for Measuring Titratable Alkalinity in Water and Wastewater - HI84531

Mini titrator for Measuring Titratable Alkalinity in Water and Wastewater Alkalinity is the ability of water to neutralize acids. Total titratable alkalinity is a measure of primarily three types of a...

Automatic Potentiometric Titrator

Automatic Potentiometric Titrator

  Superior design for the busy lab. The Cycoloy® body is durable, heat-resistant, and resists staining. Dedicated menu buttons are part of the control panel making it fully sealed and easy to clean. A...

HI931 and HI932 Series

Automatic Potentiometric Titrators

1. Highest Dosing Accuracy

  • 40,000-Step Pump
  • Dosages from 0.125 µl

2. New Interface

  • High-Contrast LCD Display with Wide Field of View, Real-Time Graphics

3. Innovative Materials

  • Cycoloy® Resin Housing: Heat and Dirt Resistant

4. Small Footprint

  • Requires only half the space of the HI90x Series Titrators

Automation with the HI510 Universal process controller

HI510

Universal Process Controller pH/EC/ORP/Temperature/DO

The HI510 is an advanced universal process controller that can be configured for many applications requiring monitoring and/or control of process parameters. It features a digital probe input that automatically detects and updates the controller with the measured parameter.

The HI510 offers options for wall, pipe, and panel mounting.

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